60/40 in millimeters
On a card whose left and right borders add up to 6 mm, 60/40 centering means a 3.6 mm border on one side and 2.4 mm on the other, a difference of 1.2 mm. Most people can see it once they look for it.
Questions
Can a 60/40 card get a PSA 10?
Not with a 60/40 front. PSA's Gem Mint 10 needs about 55/45 or better on the front. On the back, 60/40 still allows a 10, since the back limit is 75/25.
Is 60/40 good centering?
60/40 is just outside gem range. It misses the 55/45 needed for a PSA or CGC 10 on the front, and points to a 9 at best.
See every ratio on the centering chart, or read the full centering requirements.